Step 1 :Find the first derivative of the function, \(f'(x)\). The derivative of \(x^{2}\) is \(2x\), the derivative of \(x\) is \(1\), and the derivative of a constant is \(0\). So, \(f'(x) = 2*8x - 3 + 0 = 16x - 3\).
Step 2 :Find the second derivative of the function, \(f''(x)\). The derivative of \(x\) is \(1\), and the derivative of a constant is \(0\). So, \(f''(x) = 16 - 0 = 16\).
Step 3 :Find \(f''(0)\) and \(f''(5)\). Since \(f''(x)\) is a constant, \(f''(0) = f''(5) = 16\).
Step 4 :So, the answers are: \(\boxed{f''(0) = 16}\) and \(\boxed{f''(5) = 16}\).