Step 1 :The dissolution of solid ammonium nitrate in water is associated with a temperature change in the solution.
Step 2 :When the solution becomes cold, it indicates that the system is absorbing heat from the surroundings.
Step 3 :This absorption of heat is a characteristic of an endothermic process.
Step 4 :An endothermic reaction is one that requires energy, usually in the form of heat, from its surroundings to proceed.
Step 5 :Since the dissolution of ammonium nitrate in water absorbs heat and causes the temperature of the solution to decrease, the correct answer is \(\boxed{\text{Endothermic}}\)