Step 1 :Calculate the decay constant \( k \) using the formula \( k = \frac{\ln(2)}{T_{1/2}} \) where \( T_{1/2} \) is the half-life of the substance.
Step 2 :Given the half-life \( T_{1/2} \) of \( ^{238} \mathrm{Pu} \) is 87.7 years, substitute this value into the formula to find \( k \): \( k = \frac{\ln(2)}{87.7} \approx 0.00790 \) (rounded to five decimal places).
Step 3 :Write the exponential decay function \( Q(t) \) using the initial quantity \( Q_0 = 3.5 \mathrm{~kg} \) and the decay constant \( k \) calculated in the previous step: \( Q(t) = 3.5 \mathrm{~kg} \cdot e^{-0.00790 \cdot t} \).
Step 4 :The final function that models the quantity of \( ^{238} \mathrm{Pu} \) left after \( t \) years is: \(\boxed{Q(t) = 3.5 e^{-0.00790 t}}\)