A 2400. -gram sample of an aqueous solution contains 0.012 gram of \( \mathrm{NH}_{3} \). What is the concentration of \( \mathrm{NH}_{3} \) in the solution, expressed as parts per million?
1. \( 5.0 \mathrm{ppm} \)
2. \( 15 \mathrm{ppm} \)
3. 20. ppm
4. 50. ppm