Step 1 :The question is asking for the probability of rolling a 3 or 5 on a 6-sided die.
Step 2 :Since there are 6 possible outcomes (1, 2, 3, 4, 5, 6) and 2 of them are favorable (3, 5), the probability is \(\frac{2}{6}\) or \(\frac{1}{3}\).
Step 3 :Final Answer: The probability of rolling a 3 or 5 on a 6-sided die is \(\boxed{\frac{1}{3}}\).