Step 1 :Given that the sample size, \(n=19\), the significance level, \(\alpha=0.025\), and the alternative hypothesis is \(H_{1}: \sigma<0.629\).
Step 2 :The degrees of freedom for a chi-square test is \(n-1\), where \(n\) is the sample size. In this case, \(n=19\), so the degrees of freedom is \(18\).
Step 3 :We want to find the critical value at the right tail of the distribution, so we need to use \(1-\alpha\) in the percent point function.
Step 4 :Substituting the given values, we get the critical value as \(31.526378440386626\).
Step 5 :Rounding off to three decimal places, the critical value of \(\chi^{2}\) is \(\boxed{31.526}\).