Step 1 :Find the gradients of the lines: $m_{L_1} = 3$, $m_{L_2} = -\frac{1}{3}$
Step 2 :Check if their product is -1: $m_{L_1} \times m_{L_2} = 3 \times -\frac{1}{3} = -1$
Step 3 :\boxed{\text{The lines } L_1 \text{ and } L_2 \text{ are perpendicular.}}