Step 1 :Given that the sample size, n = 146 and the sample standard deviation, s = 1.96, we can calculate the degrees of freedom as df = n - 1 = 146 - 1 = 145.
Step 2 :Using a chi-square distribution table or a statistical calculator, with the degrees of freedom as 145 and the confidence level as 99%, we find the critical values as \(\chi_{L}^{2} = 104.89\) and \(\chi_{R}^{2} = 192.61\).
Step 3 :We can then calculate the confidence interval estimate of \(\sigma\) using the formula \(\sqrt{\frac{(n-1)s^2}{\chi_{R}^{2}}} < \sigma < \sqrt{\frac{(n-1)s^2}{\chi_{L}^{2}}}\). Substituting the given values, we get \(\sqrt{\frac{(145)(1.96)^2}{192.61}} < \sigma < \sqrt{\frac{(145)(1.96)^2}{104.89}}\), which simplifies to \(1.70 < \sigma < 2.30\).
Step 4 :So, the degrees of freedom is \(\boxed{145}\), the critical value \(\chi_{L}^{2}\) is \(\boxed{104.89}\), the critical value \(\chi_{R}^{2}\) is \(\boxed{192.61}\), and the confidence interval estimate of \(\sigma\) is \(\boxed{1.70}(1000 \text{ cells } / \mu \mathrm{L}) < \sigma < \boxed{2.30}(1000 \text{ cells } / \mu \mathrm{L})\).